Kinetic analysis of overlapping multistep thermal decomposition comprising exothermic and endothermic processes: thermolysis of ammonium dinitramide
نویسندگان
چکیده
منابع مشابه
Kinetic analysis of overlapping multistep thermal decomposition comprising exothermic and endothermic processes: thermolysis of ammonium dinitramide.
This study focused on kinetic modeling of a specific type of multistep heterogeneous reaction comprising exothermic and endothermic reaction steps, as exemplified by the practical kinetic analysis of the experimental kinetic curves for the thermal decomposition of molten ammonium dinitramide (ADN). It is known that the thermal decomposition of ADN occurs as a consecutive two step mass-loss proc...
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The thermal decomposition of ammonium dinitramide, NH4N(NO2)2 (ADN), in the gas phase has been studied at 373–920 K by pyrolysis/mass spectrometry under low-pressure conditions using a Saalfeld reactor. The reaction of the sublimed mixture of NH3 and HN(NO2)2 (dinitraminic acid, DN) was found to be initiated by the unimolecular decomposition of DN, HN(NO2)2 → HNNO2 ` NO2, followed by the rapid ...
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ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2017
ISSN: 1463-9076,1463-9084
DOI: 10.1039/c6cp08218a